Degradation Kinetics of Time-Dependence of Molecular Weight Distributions
نویسنده
چکیده
zC C 4 Z' ;e: : ; ; " f fL-3 =A "Polymer degradation occurs when polymer ciains are broken under the influence of 3= 2; J:
منابع مشابه
Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst.
In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated. For this purpose the molecular weight distributions of the samples were deconvoluted to the minimum number of Flor...
متن کاملThermal Degradation Kinetics of Para-Substituted Poly (styrene Peroxide)s in Solution
The thermal degradation of three polymeric peroxides of styrene monomers with substituents in the para position was studied at various temperatures (65, 75, 85, and 95°C). A continuous distribution model was used to evaluate the rate coefficients for the random-chain and chain-end scission degradation from the evolution of molecular weight distributions with time. The activation energy determin...
متن کاملNon-Isothermal Degradation Kinetics of High Energy Protons Irradiated Polyvinyl Butyral
This research is aimed to undertake a comparative study on stability and thermal degradation kinetics of un-irradiated and high energy protons irradiated polyvinyl butyral (PVB) based on weight loss analysis and non-isothermal approaches. The weight loss by the un-irradiated PVB upon heating was found to be in two stages but due to high energy protons accelerated exposure following by chemical ...
متن کاملEffect of alkyl group substituents on the degradation of poly ( alkyl methacrylates ) in supercritical fluids
The effect of alkyl group substituents on the degradation kinetics of poly(alkyl methacrylates) namely poly (n-butyl methacrylate) (PBMA), poly (iso-propyl methacrylate) (PPMA), poly (ethyl methacrylate) (PEMA), and poly (methyl methacrylate) (PMMA) in supercritical and subcritical conditions was studied at various temperatures (250 – 375 o C). The molecular weight distributions were measured b...
متن کاملThe Photocatalytic, Thermal Degradation Kinetics and Lifetime Prediction of Some Commercial Reactive Dyes
The photocatalytic degradation of the commercial reactive Black5 (RB5), Blue19 (RB19), Green19 (RG19), Red120 (RR120), and Yellow81 (RY81) in aqueous solution and sunlight were examined in the presence of Fe2O3 and the mixture Fe2O3/H2O2 as catalysts. The results showed that the photocatalytic degradation followed first-order...
متن کامل